I've always been against grounding probes, there's some talk that streaming voltage like that can cause HLLE, but of course, what doesn't cause HLLE...
When I first had this issue, it was as Torx suggested, turn off each item in the sump and try the finger. If it's just salt sensitivity it will only happen the first time, if it's voltage it will be every time. Turn things off until it stops, and that's the culprit. Usually it's an issue with the epoxy in a motor, saltwater gets in there and either rusts/bloats the device, and/or it leaks just enough voltage not to trip the GFCI ( if you don't have one, get one, it could save your life!).
For me, the issue was healthy sps turning into very unhappy sps. When the voltage goes up it affects more and more types of coral. stn turns to rtn.